Phosphate treatment is preferred in
drum type boilers. In this Phosphate especially Tri sodium phosphate is added at
the boiler drum which is operating at high pressure (so called HP dosing
system) through HP dosing system.
If it is dosed at feed pipe, it may
react with impurities and sludge may be deposited at the feed line.
Tri sodium Phosphate
(TSP) is generally used for HP dosing. This is directly dosed into steam drum
to remove carbonate & bicarbonate scale sludge & to increase pH. Phosphate
reacts with calcium and magnesium forms less sticky, loose and non-adherent
sludge instead of hard scale. This sludge remains in the boiler water in
suspended condition and then, removed from the boiler through blow down Other
than TSP, disodium phosphate (Na2HPO4) and monosodium phosphate (NaH2PO4) are
used in boiler for dosing.
CONSIDERATIONS & ASSUMPTIONS FOR SYSTEM DESIGN:
1. Boiler capacity, operating pressure & temperatures
be 100 TPH, 110 kg/cm2 & 530 deg C respectively
2-Residual Phosphate in drum water be 8ppm (Acceptable
range 5 to 10ppm)
3-Residual Hydrazine in feed water collected at BFP
outlet be 0.02ppm
4-Make up water requirement is 5%
5-Boiler maximum possible TDS be 50ppm
7-Feed water TDS be 5ppm
Let us calculate phosphate consumption
Percentage of blow down =Make up % X Feed TDS / (Boiler
TDS-Feed TDS)
= (5/100) X 5 X 100 / (50-5) =0.55%
Water loss in blow down = 100 X 0.55/100 =0.55 TPH =550
kg/hr
Loss of phosphate in blow down water = (Residual
phosphate X Blow down) / 1000
=8 X 550 / 1000 =4.4 Gm/hr
Consumption of TSP in Gm/hr = Residual phosphate X
Phosphate loss = 8 X 4.4 =35.2 gm/hr
Consumption of TSP in a day in kg = 35.2 X 24 /1000 =0.85
kg/day
That is we need to dose 0.85 kg of TSP in a day to
maintain phosphate level & pH in drum water
So phosphate dosing in mg/liter or ppm = 0.85 X 106
/ (100*1000 X 24) =0.35
So per hour we have to dose (0.35 X 100 X 1000) / 1000
=35 gram of TSP into steam drum.
Pump selection
Considerations:
1-Pump type is positive displacement plunger type
2-Discharge pressure = Drum operating pressure X 110%
=115 X 110% = 126.5 kg/cm2, select 130 kg/cm2
3-Pump will be operated at 50% (Can operate up to 75%)
stroke to avoid frequent maintenance issues.
4-TSP solution is prepared twice in a day (0.88 / 2 =0.44
kg / half day)
Now we have to choose a pump for dosing TSP
There for Total solution of TSP to be dosed in Boiler
water at 15 LPH @ 50% stroke (Standard dosing required is 12-15 LPH for 100 TPH
boiler)
So pump rated capacity = 15 X 2 = 30 LPH (At 100% stroke)
Note:
Selection of pump stroke depends on pump capacity &
maintenance reliability. So better to operate the pump at 50% stroke
Tank selection:
Select a cylindrical tank
Capacity of the tank = Maximum operating stroke X 24 =30
X 24 =720 liters
Optimum size of the tank = Operating stroke X 24 hours X
115% =15 X 24 X 120% = 432 liters
Select tank capacity = 450 litres
Note:
Pump can be operated at higher stroke by reducing the
concentration of TSP in tank
Pump can be operated even at less stroke (<50%) if TSP
concentration in tank is increased
But standard practice is to dose chemical at higher flow
rate with less chemical concentration to get good result.
very good information keep it up nyc.
ReplyDeleteNYC
ReplyDeleteInformative
ReplyDeletecan you please explain me step "Consumption of TSP = Residual phosphate x Phosphate Loss" . Thanks
ReplyDeleteI am bit confused why it must be multiplied by 8 again? Shouldn't "Loss of Phosphate" be equal to "Consumption of TSP"? Thanks.
ReplyDelete